Lithium, Lithium-ion, LiPo & LiFePO4 Battery Safety and Fire Handling
by David Kohanbash on November 14, 2017
Lithium battery safety is an important issue as there are more and more reports of fires and explosions. Fires have been reported in everything from cell phones to airplanes to robots.
If you don’t know why we need to discuss this, or even if you do know, watch this clip or click here.
I am not a fire expert. This post is based on conversations with experts and some basic research. Contact your local fire department for advice specific to your situation. I had very little success contacting my local fire department about this, hopefully you will have more luck.
Preventing Problems
1. Use a proper charger for your battery type and voltage. This will help prevent overcharging. In many cases lithium-ion batteries catch fire when the chargers keep dumping charge into the batteries after the maximum voltage has been reached.
2. Use a battery management system (BMS) when building battery packs with multiple cells. A BMS will monitor the voltage of each cell and halt charging when any cell reaches the maximum voltage. Cheap BMS’s will stop all charging when any cell reaches that maximum voltage. Fancier/better BMS’s can individually charge each cell to help keep the battery pack balanced. A balanced pack is good since each cell will be a similar voltage for optimal battery pack performance. The fancy BMS’s can also often detect if a single cell is reading wrong. There have been cases of a BMS’s working properly but a single cell going bad which confuses the BMS; and yields a fire/explosion.
3. Only charge batteries in designated areas. A designated area should be non combustible. For example cement, sand, cinder block and metal boxes are not uncommon to use for charging areas. For smaller cells you can purchase fire containment bags designed to put the charging battery in.
In addition the area where you charge the batteries should have good ventilation.
I have heard that on the Boeing Dreamliner, part of the solve for their batteries catching fire on planes, was to make sure that the metal enclosure that the batteries were in could withstand the heat of a battery fire. And also to make sure that in the event of a fire the fumes would vent outside the aircraft and not into the cabin.
Dreamliner battery pack before and after fire. [SOURCE]
5. Avoid connecting battery packs in parallel (with no BMS). If the voltage on each battery pack is different (ie. unbalanced) then one of the batteries can push a lot of charge to the other batteries. This can also yield a fire.
6. Don’t leave batteries unattended when charging. This will let people be available in case of a problem. However, as you saw in the video above, you might want to keep a distance from the battery in case there is a catastrophic event with flames shooting out from the battery pack.
I have seen several designs for self-contained charging stations for extinguishing fires. Most of them involve suspending sandbags over the charging station. If the plastic bags holding the sand melts, all of the sand will fall on the batteries and smother the fire. See youtube for some examples.
7. Store batteries within the specs of the battery. Usually that means room temperature and out of direct sunlight (to avoid overheating). Also charging lithium batteries in extreme cold can cause internal battery damage that will cause a fire during subsequent charges.
8. Training of personnel for handling batteries, charging batteries, and what to do in the event of a fire. Having people trained in what to do can be important so that they stay safe. For example, without training people might not realize how bad the fumes are. Also make sure people know where the fire pull stations are and where the extinguishers are.
9. Don’t attempt to charge lithium cells that have been over-discharged, as over-discharging the cell can result in damage to the cell that can cause future charge cycles to catch fire. Over-discharging can happen if the cell is discharged without proper BMS electronics or if the battery is left to sit for extended periods of time (years) and self-discharges.
10. Visually inspect the battery for defects before charging and using. If any bulging, punctures, burn marks, etc.. are found, do not use the batteries. Dispose of the batteries in a safe manner. If you are being very good, you can caliper the batteries from time to time to make sure their is no bulging.
11. After flying a drone, wait a little before charging the battery in case the battery got hot.
12. Avoid using/charging batteries in carpeted areas (or around other combustible items), so if there is a fire there is less chance of it spreading.
Handling Fires
1. There are 2 primary issues with a lithium fire. The fire itself and the gases released. This means that even if you think you can safely extinguish the fire, you need to keep in mind the fumes and possibly clear away from the fire.
2a. Lithium batteries which are usually in the form of small non-rechargeable batteries (such as in a watch) in theory require a class D fire extinguisher. However most people do not have one available. As such, for the most part you need to just let it burn itself out (it is good that the batteries are usually small). You can use a standard class ABC fire extinguisher to prevent the spread of the fire. Avoid using water on the lithium battery itself since the lithium and water can react violently.
2b. Lithium-ion batteries (including LiFePO4, etc…) that are used on many robots, are often larger and rechargeable. For these batteries there is not a lot of actual lithium metal in the battery, so you can use water, class ABC fire extinguisher, or CO2 extinguisher. The CO2 extinguisher are often nice since they do not leave a bad residue on your electronics. You do not use a class D extinguisher with these batteries. You will most likely need a lot of water or extinguishers.
With both of these types of fires, there is a good chance that you will not be able to extinguish it. There is also a good chance that by the time you get an extinguisher the battery part of the fire will be out, and you will be dealing with surrounding combustibles that are on fire. If you can safety be in the area your primary goal is to allow the battery to burn in a controlled and safe manner. If possible try to get the battery outside and on a surface that is not combustible. As a reminder lithium-ion fires are very hot and flames can shoot out from various places unexpectedly; you need to be careful and only do what you can do safety. If you have a battery with multiple cells it is not uncommon for each cell to catch fire separately. So you might see the flames die down, then shortly after another cell catches fire, and then another; as the cells cascade and catch fire.
A quick reminder about how to use a fire extinguisher. Remember first you Pull the pin, then you Aim at the base of the fire, then you Squeeze the handle, followed by Sweeping back and forth at the base of the fire. [SOURCE]
Update: Somebody pointed me to these new fire extinguishers designed for Lithium ion batteries as are often used in robotics https://www.avdfire.com/products/lith-ex-9-litre-fire-extinguisher/
3. In many cases the batteries are in an enclosure where if you spray the robots with an extinguisher you will not even reach the batteries. In this case your priority is your safety (from fire and fumes), followed by preventing the fire from spreading. To prevent the fire from spreading you need to make sure all combustible material is away from the robot. If possible get the battery pack outside.
In firefighting school a common question is: Who is the most important person? To which the response is, me!
4. If charging the battery, try to unplug the battery charger from wall. Again only if you can do this safely. Electricity should be disconnected before dousing the fire with water.
I hope you found the above useful. I am not an expert on lithium batteries or fire safety. Consult with your local experts and fire authorities. I am writing this post due to the lack of information in the robotics community about battery safety.
As said by Wired “you know what they say: With great power comes great responsibility.”.
Click here for more information about various types of batteries.
Thank you Jeff (I think he said I should call him Merlin) for some help with this topic.
Edit: He has since asked for me to call him Jedi1.
Comments
Great article. If I may, I would like to add a few points:
-When possible, only buy cells or batteries from reputable manufacturers. In order to be shipped via air, all lithium batteries must undergo UN testing for transportation of dangerous goods. When in doubt, ask the vendor for the documentation (self-certification is acceptable). Note that batteries and cells are tested separately so if you buy cells and pack them yourself, you will have to get the battery tested prior to shipping.
-Don’t charge lithium batteries in extreme cold environments. This can cause damage to the cell that can cause future charge cycles to catch fire.
-Don’t attempt to charge lithium cells that have been over-discharged, as over-discharging the cell can result in damage to the cell that can cause future charge cycles to catch fire. Over-discharging can happen if the cell is discharged without proper BMS electronics or if the battery is left to sit for extended periods of time (years) and self-discharges.
-The preferred method for fighting lithium-ion battery fires is large quantities of water. Once a cell is in thermal runaway, there is no real way to stop it. What the water does is cools everything down to hopefully stop the cell-to-cell propagation and can extinguish fires of secondary flammable materials. It goes without saying that the water should not be used if the system is plugged in.
Those are all great points. I have added a lot of that to the post above.
As always thanks for the feedback and for reading!